1 Recent progress in materials used towards corrosion protection of Mg and its alloys https://jourcc.com/index.php/jourcc/article/view/jcc245 10.29252/jcc.2.4.5 20.1001.1.26765837.2020.2.5.5.9 1 Magnesium has little resistance to corrosion and therefore its production and use are quite limited. The problem of corrosion associated with these alloys has been alleviated to some extent by the advantages obtained from fine coatings. An additional dense barrier against corrosion is created, using coatings obtained from sol-gel. As an alternative for Cr-based conversion coatings, rare-earth elements-based ones are been increasingly investigated for Mg and its alloys due to being eco-friendly. Because of chemical inertness, low friction, and high hardness, diamond-like carbon (DLC) coatings have exhibited the best protection for Mg and its alloys. In this review, we shed light on recent advancements in novel coatings for Mg alloys including hybrid, rare-earth conversion, composite polymeric (polymer composite is a multi-phase material in which reinforcing fillers are integrated with a polymer matrix), and DLC coatings. 205 214 Hadi Ghazanfari Université Laval Canada hadi.ghazanfari.1@ulaval.ca Saber Hasanizadeh Kermanshah University of Technology Iran info@jourcc.com Sara Eskandarinezhad Yazd University Iran info@jourcc.com Soheil Hassani Scince and Research Branch, Islamic Azad University (IAU) Iran info@jourcc.com Mohsen Sheibani Shiraz Branch, Islamic Azad University (IAU) Iran info@jourcc.com Alireza Dordsheikh Torkamani Iran University of Science and Technology (IUST) Iran info@jourcc.com Belma Fakić University of Zenica Zenica info@jourcc.com Hybrid coatings Rare-earth Polymeric composite DLC coatings Article5.pdf [1] J. Gray, B. Luan, Protective coatings on magnesium and its alloys—a critical review, Journal of alloys and compounds 336(1-2) (2002) 88-113. ##[2] A.H. Shahbaz, M. Esmaeilian, R. NasrAzadani, K. Gavanji, The effect of MgF2 addition on the mechanical properties of hydroxyapatite synthesized via powder metallurgy, Journal of Composites and Compounds 1(1) (2019) 18-24. ##[3] A. Moghanian, A. Ghorbanoghli, M. Kazem‐Rostami, A. Pazhouheshgar, E. Salari, M. Saghafi Yazdi, T. Alimardani, H. Jahani, F. Sharifian Jazi, M. Tahriri, Novel antibacterial Cu/Mg‐substituted 58S‐bioglass: Synthesis, characterization and investigation of in vitro bioactivity, International Journal of Applied Glass Science 11(4) (2020) 685-698. ##[4] H. Liu, F. Cao, G.-L. Song, D. Zheng, Z. Shi, M.S. Dargusch, A. Atrens, Review of the atmospheric corrosion of magnesium alloys, Journal of Materials Science and Technology 35(9) (2019) 2003-2016. ##[5] D. Tawil, Corrosion and surface protection developments, magnesium technology, Proceedings of the Conference, 1986. ##[6] M. Shahin, K. Munir, C. Wen, Y. Li, Magnesium matrix nanocomposites for orthopedic applications: a review from mechanical, corrosion, and biological perspectives, Acta biomaterialia 96 (2019) 1-19. ##[7] M.F. Heragh, S. Eskandarinezhad, A. Dehghan, Ni-Cu matrix composite reinforced with CNTs: preparation, characterization, wear and corrosion behavior, inhibitory effects, Journal of Composites and Compounds 2(4) (2020) 123-128. ##[8] M. Amiri, V.T. Targhi, S. Padervand, S.M.M. Khoei, Corrosion behavior of aluminum oxide coatings created by electrolytic plasma method under different potential regimes, Journal of Composites and Compounds 2(4) (2020) 129-137. ##[9] M. Amiri, S. Padervand, V.T. Targhi, S.M.M. Khoei, Investigation of aluminum oxide coatings created by electrolytic plasma method in different potential regimes, Journal of Composites and Compounds 2(4) (2020) 115-122. ##[10] A. Abuchenari, H. Ghazanfari, M. Siavashi, M. Sabetzadeh, S. Talebi, Z.K. Chemeh, A. Jamavari, A review on development and application of self-healing thermal barrier composite coatings, Journal of Composites and Compounds 2(4) (2020) 147-154. ##[11] S. Lamaka, M. Montemor, A. Galio, M. Zheludkevich, C. Trindade, L. Dick, M. Ferreira, Novel hybrid sol–gel coatings for corrosion protection of AZ31B magnesium alloy, Electrochimica Acta 53(14) (2008) 4773-4783. ##[12] F.S. Jazi, N. Parvin, M. Rabiei, M. Tahriri, Z.M. Shabestari, A.R. Azadmehr, Effect of the synthesis route on the grain size and morphology of ZnO/Ag nanocomposite, Journal of Ceramic Processing Research 13(5) (2012) 523-526. ##[13] C. Lin, S. Fang, Formation of cerium conversion coatings on AZ31 magnesium alloys, Journal of the Electrochemical Society 152(2) (2004) B54. ##[14] F.S. Jazi, N. Parvin, M. Tahriri, M. Alizadeh, S. Abedini, M. Alizadeh, The relationship between the synthesis and morphology of SnO2-Ag2O nanocomposite, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 44(5) (2014) 759-764. ##[15] Q. Cheng, X. Guo, X. Hao, Z. Shi, S. Zhu, Z. Cui, Fabrication of Robust Antibacterial Coatings Based on an Organic–Inorganic Hybrid System, ACS applied materials and interfaces 11(45) (2019) 42607-42615. ##[16] S.V. Gnedenkov, S.L. Sinebryukhov, D.V. Mashtalyar, V.S. Egorkin, M.V. Sidorova, A.S. Gnedenkov, Composite polymer-containing protective coatings on magnesium alloy MA8, Corrosion Science 85 (2014) 52-59. ##[17] J. Daraei, Production and characterization of PCL (Polycaprolactone) coated TCP/nanoBG composite scaffolds by sponge foam method for orthopedic applications, Journal of Composites and Compounds 2(1) (2020) 45-50. ##[18] M. Arefian, M. Hojjati, I. Tajzad, A. Mokhtarzade, M. Mazhar, A. Jamavari, A review of Polyvinyl alcohol/Carboxiy methyl cellulose (PVA/CMC) composites for various applications, Journal of Composites and Compounds 2(3) (2020) 69-76. ##[19] A. Zomorodian, M. Garcia, T.M. e Silva, J. Fernandes, M. Fernandes, M. Montemor, Corrosion resistance of a composite polymeric coating applied on biodegradable AZ31 magnesium alloy, Acta Biomaterialia 9(10) (2013) 8660-8670. ##[20] J. Choi, S. Nakao, J. Kim, M. Ikeyama, T. Kato, Corrosion protection of DLC coatings on magnesium alloy, Diamond and Related Materials 16(4) (2007) 1361-1364. ##[21] X.-J. Cui, C.-M. Ning, L.-L. Shang, G.-A. Zhang, X.-Q. Liu, Structure and anticorrosion, friction, and wear characteristics of Pure Diamond-Like Carbon (DLC), Cr-DLC, and Cr-H-DLC films on AZ91D Mg alloy, Journal of Materials Engineering and Performance 28(2) (2019) 1213-1225. ##[22] T. Nakatani, H. Takeuchi, A. Wada, S. Yamashita, Investigation of Anti-Corrosive Performance of a Si-Doped DLC-Coated Magnesium Alloy Stent Deposited by RF-Plasma CVD, Journal of Photopolymer Science and Technology 32(3) (2019) 511-517. ##[23] K. Zhanga, Q. Van Leb, Journal of Composites and Compounds, (2019). ##[24] C. Niranjan, S. Srinivas, M. Ramachandra, An experimental study on depth of cut of AZ91 Magnesium Alloy in abrasive water jet cutting, Materials Today: Proceedings 5(1) (2018) 2884-2890. ##[25] N. Studio, Magnesium and exercise-Blog, (2020). ##[26] L.S. Fard, N.S. Peighambardoust, H.W. Jang, A. Dehghan, N.N.K. Saligheh, M. Iranpour, M.I. Rajabi, The rechargeable aluminum-ion battery with different composite cathodes: A review, Journal of Composites and Compounds 2(4) (2020) 138-146. ##[27] S. Nasibi, K. Alimohammadi, L. Bazli, S. Eskandarinezhad, A. Mohammadi, N. Sheysi, TZNT alloy for surgical implant applications: A systematic review, Journal of Composites and Compounds 2(3) (2020) 62-68. ##[28] K. Zhang, H.W. Jang, Q. Van Le, Production methods of ceramic-reinforced Al-Li matrix composites: A review, Journal of Composites and Compounds 2(3) (2020) 77-84. ##[29] J.-L. Kuo, S. Sugiyama, S.-H. Hsiang, J. Yanagimoto, Investigating the characteristics of AZ61 magnesium alloy on the hot and semi-solid compression test, The International Journal of Advanced Manufacturing Technology 29(7-8) (2006) 670-677. ##[30] X. He, B. Dong, Y. Chen, R. Li, F. Wang, J. Li, Z. Cai, Analysis of magnesium and copper in aluminum alloys with high repetition rate laser-ablation spark-induced breakdown spectroscopy, Spectrochimica Acta Part B: Atomic Spectroscopy 141 (2018) 34-43. ##[31] I. Tajzad, E. Ghasali, Production methods of CNT-reinforced Al matrix composites: a review, Journal of Composites and Compounds 2(1) (2020) 1-9. ##[32] F. Sharifianjazi, M. Moradi, A. Abouchenari, A.H. Pakseresht, A. Esmaeilkhanian, M. Shokouhimehr, M.S. Asl, Effects of Sr and Mg dopants on biological and mechanical properties of SiO2–CaO–P2O5 bioactive glass, Ceramics International (2020). ##[33] A. Bordbar-Khiabani, B. Yarmand, M. Mozafari, Emerging magnesium-based biomaterials for orthopedic implantation, Thomas Telford Ltd, 2019. ##[34] K. Singh, G. Singh, H. Singh, Review on friction stir welding of magnesium alloys, Journal of magnesium and alloys 6(4) (2018) 399-416. ##[35] K. Singh, G. Singh, H. Singh, Investigation of microstructure and mechanical properties of friction stir welded AZ61 magnesium alloy joint, Journal of Magnesium and Alloys 6(3) (2018) 292-298. ##[36] H. Somekawa, A. Kinoshita, A. Kato, Effect of alloying elements on room temperature stretch formability in Mg alloys, Materials Science and Engineering: A 732 (2018) 21-28. ##[37] R. Galun, A. Weisheit, B. Mordike, Laser surface alloying of magnesium base alloys, Journal of Laser Applications 8(6) (1996) 299-305. ##[38] M. Easton, M.A. Gibson, S. Zhu, T. Abbott, J.-F. Nie, C.J. Bettles, G. Savage, Development of magnesium-rare earth die-casting alloys, TMS Annual Meeting and Exhibition, Springer, 2018, pp. 329-336. ##[39] E. Aghion, B. Bronfin, Magnesium alloys development towards the 21st century, Materials Science Forum, Trans Tech Publ, 2000, pp. 19-30. ##[40] A. Abuchenari, M. Moradi, The Effect of Cu-substitution on the microstructure and magnetic properties of Fe-15% Ni alloy prepared by mechanical alloying, Journal of Composites and Compounds 1(1) (2019) 11-17. ##[41] R. Pandey, S. Tekumalla, M. Gupta, Effect of defects on electromagnetic interference shielding effectiveness of magnesium, Journal of Materials Science: Materials in Electronics 29(11) (2018) 9728-9739. ##[42] S. Ben Zaken, O. Simantov, A. Abenstein, Z. Radomysky, G. Koren, Water desalination, serum magnesium and dementia: a population-based study, Journal of Water and Health 18(5) (2020) 722-727. ##[43] A.A. Luo, Magnesium casting technology for structural applications, journal of Magnesium and Alloys 1(1) (2013) 2-22. ##[44] H. Hu, Squeeze casting of magnesium alloys and their composites, Journal of materials science 33(6) (1998) 1579-1589. ##[45] H. Dieringa, K.U. Kainer, Magnesium and Magnesium Alloys, Springer Handbook of Materials Data, Springer2018, pp. 151-159. ##[46] R.H. Buzolin, P. Volovitch, A. Maltseva, S. Lamaka, C. Blawert, C.L. Mendis, A. Lohmüller, K.U. Kainer, N. Hort, Thixomolded AZ91D and MRI153M magnesium alloys and their enhanced corrosion resistance, Materials and corrosion 71(3) (2020) 339-351. ##[47] B. Viswanadhapalli, V.B. Raja, Application of Magnesium Alloys in Automotive Industry-A Review, International Conference on Emerging Current Trends in Computing and Expert Technology, Springer, 2019, pp. 519-531. ##[48] R. Viswanathan, N. Sivashankar, S. Chandrakumar, R. Karthik, Improving Corrosion Resistance of Magnesium Alloy for Aerospace Applications, International Journal of Mechanical and Production Engineering Research and Development 9(3) (2019) 769-774. ##[49] O.I. Velikokhatnyi, P.N. Kumta, First-principles studies on alloying and simplified thermodynamic aqueous chemical stability of calcium-, zinc-, aluminum-, yttrium-and iron-doped magnesium alloys, Acta Biomaterialia 6(5) (2010) 1698-1704. ##[50] M. Bian, X. Huang, Y. Chino, Improving flame resistance and mechanical properties of magnesium–silver–calcium sheet alloy by optimization of calcium content, Journal of Alloys and Compounds (2020) 155551. ##[51] M. Esmaily, J. Svensson, S. Fajardo, N. Birbilis, G. Frankel, S. Virtanen, R. Arrabal, S. Thomas, L. Johansson, Fundamentals and advances in magnesium alloy corrosion, Progress in Materials Science 89 (2017) 92-193. ##[52] A. Toulabifard, M. Rahmati, K. Raeissi, A. Hakimizad, M. Santamaria, The Effect of Electrolytic Solution Composition on the Structure, Corrosion, and Wear Resistance of PEO Coatings on AZ31 Magnesium Alloy, Coatings 10(10) (2020) 937. ##[53] R. Ambat, N.N. Aung, W. Zhou, Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy, Corrosion science 42(8) (2000) 1433-1455. ##[54] C.H. Chang, K.-T. Wu, C.-T. Lin, Magnesium Alloy Substrate, Google Patents, 2018. ##[55] C. Li, H. Huang, J. Zhao, S. Ruan, A high strength magnesium alloy-based rotating mirror for an ultra-high speed camera, Optik 157 (2018) 85-92. ##[56] G. Song, A.L. Bowles, D.H. StJohn, Corrosion resistance of aged die cast magnesium alloy AZ91D, Materials Science and Engineering: A 366(1) (2004) 74-86. ##[57] D. Klaumünzer, J.V. Hernandez, S. Yi, D. Letzig, S.-h. Kim, J.J. Kim, M.H. Seo, K. Ahn, Magnesium process and alloy development for applications in the automotive industry, Magnesium Technology 2019, Springer2019, pp. 15-20. ##[58] G. Demir, A.U. Malcıoğlu, S. Sağdiç, A. Ulus, S. Aslanlar, E. İlhan, Optimization of Thermo-Mechanical Processes of Continuous Casting Products Using High Magnesium Aluminum Alloys in Automotive Industry Applications, Light Metals 2020, Springer2020, pp. 386-399. ##[59] H. Friedrich, S. Schumann, Research for a “new age of magnesium” in the automotive industry, Journal of Materials Processing Technology 117(3) (2001) 276-281. ##[60] S. Schumann, The paths and strategies for increased magnesium applications in vehicles, Materials Science Forum, Trans Tech Publ, 2005, pp. 1-8. ##[61] M.K. Kulekci, Magnesium and its alloys applications in automotive industry, The International Journal of Advanced Manufacturing Technology 39(9-10) (2008) 851-865. ##[62] F. Czerwinski, Controlling the ignition and flammability of magnesium for aerospace applications, Corrosion Science 86 (2014) 1-16. ##[63] T. Kaneko, M. Suzuki, Automotive applications of magnesium alloys, Materials science forum, Trans Tech Publications Ltd., Zurich-Uetikon, Switzerland, 2003, pp. 67-72. ##[64] P.R. Matli, A.V. Krishnan, V. Manakari, G. Parande, B. Chua, S. Wong, C. Lim, M. Gupta, A new method to lightweight and improve strength to weight ratio of magnesium by creating a controlled defect, Journal of Materials Research and Technology (2020). ##[65] M.P. Staiger, A.M. Pietak, J. Huadmai, G. Dias, Magnesium and its alloys as orthopedic biomaterials: a review, Biomaterials 27(9) (2006) 1728-1734. ##[66] N.-E.L. Saris, E. Mervaala, H. Karppanen, J.A. Khawaja, A. Lewenstam, Magnesium: an update on physiological, clinical and analytical aspects, Clinica chimica acta 294(1-2) (2000) 1-26. ##[67] J.M. Seitz, R. Eifler, F.W. Bach, H. Maier, Magnesium degradation products: effects on tissue and human metabolism, Journal of biomedical materials research Part A 102(10) (2014) 3744-3753. ##[68] T.C. Wallace, Combating COVID-19 and building immune resilience: a potential role for magnesium nutrition?, Journal of the American College of Nutrition (2020) 1-9. ##[69] F. Ahmed, A. Mohammed, Magnesium: the forgotten electrolyte—a review on hypomagnesemia, Medical Sciences 7(4) (2019) 56. ##[70] D. Song, C. Li, N. Liang, F. Yang, J. Jiang, J. Sun, G. Wu, A. Ma, X. Ma, Simultaneously improving corrosion resistance and mechanical properties of a magnesium alloy via equal-channel angular pressing and post water annealing, Materials and Design 166 (2019) 107621. ##[71] D. Seifzadeh, A. Haghighat, Formation of rare earth-permanganate conversion coating on AZ61 magnesium alloy and its properties, (2013). ##[72] S. Kamrani, C. Fleck, Biodegradable magnesium alloys as temporary orthopaedic implants: a review, BioMetals 32(2) (2019) 185-193. ##[73] K. Jafarzadeh, T. Shahrabi, S. Hadavi, M. Hosseini, EIS study on corrosion behavior of AA5083-H321 aluminum-magnesium alloys in stagnant NaCl solution, (2008). ##[74] L. Liu, M. Schlesinger, Corrosion of magnesium and its alloys, Corrosion Science 51(8) (2009) 1733-1737. ##[75] F. Gao, Y. Hu, Z. Gong, T. Liu, T. Gong, S. Liu, C. Zhang, L. Quan, B. Kaveendran, C. Pan, Fabrication of chitosan/heparinized graphene oxide multilayer coating to improve corrosion resistance and biocompatibility of magnesium alloys, Materials Science and Engineering: C 104 (2019) 109947. ##[76] I. Apachitei, L. Fratila-Apachitei, J. Duszczyk, Microgalvanic activity of an Mg–Al–Ca-based alloy studied by scanning Kelvin probe force microscopy, Scripta Materialia 57(11) (2007) 1012-1015. ##[77] G. Song, B. Johannesson, S. Hapugoda, D. StJohn, Galvanic corrosion of magnesium alloy AZ91D in contact with an aluminium alloy, steel and zinc, Corrosion Science 46(4) (2004) 955-977. ##[78] R. Ambat, N.N. Aung, W. Zhou, Effect of pH and chloride ion concentration on the corrosion and electrochemical behaviour of AZ91D magnesium alloy, Journal of Applied Electrochemistry 30 (2000) 865-874. ##[79] S. Mathieu, C. Rapin, J. Steinmetz, P. Steinmetz, A corrosion study of the main constituent phases of AZ91 magnesium alloys, Corrosion Science 45(12) (2003) 2741-2755. ##[80] M. Jönsson, D. Persson, D. Thierry, Corrosion product formation during NaCl induced atmospheric corrosion of magnesium alloy AZ91D, Corrosion Science 49(3) (2007) 1540-1558. ##[81] X. Gu, Y. Zheng, Y. Cheng, S. Zhong, T. Xi, In vitro corrosion and biocompatibility of binary magnesium alloys, Biomaterials 30(4) (2009) 484-498. ##[82] S. Abbasi, M. Aliofkhazraei, H. Mojiri, M. Amini, M. Ahmadzadeh, M. Shourgeshty, Corrosion behavior of pure Mg and AZ31 magnesium alloy, Protection of Metals and Physical Chemistry of Surfaces 53(3) (2017) 573-578. ##[83] N. Liu, W. Huang, DSC study on temperature memory effect of NiTi shape memory alloy, Transactions of Nonferrous Metals Society of China 16 (2006) s37-s41. ##[84] A. Coy, F. Viejo, P. Skeldon, G. Thompson, Susceptibility of rare-earth-magnesium alloys to micro-galvanic corrosion, Corrosion Science 52(12) (2010) 3896-3906. ##[85] M. Toorani, M. Aliofkhazraei, Review of electrochemical properties of hybrid coating systems on Mg with plasma electrolytic oxidation process as pretreatment, Surfaces and Interfaces 14 (2019) 262-295. ##[86] T. Cain, L. Bland, N. Birbilis, J. Scully, A compilation of corrosion potentials for magnesium alloys, Corrosion 70(10) (2014) 1043-1051. ##[87] P. Huang, J.-A. Latham, D.R. MacFarlane, P.C. Howlett, M. Forsyth, A review of ionic liquid surface film formation on Mg and its alloys for improved corrosion performance, Electrochimica Acta 110 (2013) 501-510. ##[88] L. Yan, M. Zhou, X. Pang, K. Gao, One-step in situ synthesis of reduced graphene oxide/Zn–Al layered double hydroxide film for enhanced corrosion protection of magnesium alloys, Langmuir 35(19) (2019) 6312-6320. ##[89] R. Arrabal, A. Pardo, M. Merino, S. Merino, P. Casajús, M. Mohedano, P. Rodrigo, Corrosion behavior of mg-al alloys with aluminum thermal spray coatings in humid and saline environments, Corrosion 65(12) (2009) 817-830. ##[90] M.M. Avedesian, H. Baker, ASM specialty handbook: magnesium and magnesium alloys, ASM international1999. ##[91] J. Li, Y. He, Y. Sun, X. Zhang, W. Shi, D. Ge, Synthesis of Polypyrrole/V2O5 Composite Film on the Surface of Magnesium Using a Mild Vapor Phase Polymerization (VPP) Method for Corrosion Resistance, Coatings 10(4) (2020) 402. ##[92] R. Molak, K. Topolski, M. Spychalski, I. Dulińska-Molak, B. Morończyk, Z. Pakieła, L. Nieużyła, M. Mazurkiewicz, M. Wojucki, A. Gebeshuber, Functional properties of the novel hybrid coatings combined of the oxide and DLC layer as a protective coating for AZ91E magnesium alloy, Surface and Coatings Technology 380 (2019) 125040. ##[93] V.Z. Asl, J. Zhao, M.J. Anjum, S. Wei, W. Wang, Z. Zhao, The effect of cerium cation on the microstructure and anti-corrosion performance of LDH conversion coatings on AZ31 magnesium alloy, Journal of Alloys and Compounds 821 (2020) 153248. ##[94] R.-G. Hu, S. Zhang, J.-F. Bu, C.-J. Lin, G.-L. Song, Recent progress in corrosion protection of magnesium alloys by organic coatings, Progress in Organic Coatings 73(2-3) (2012) 129-141. ##[95] J. Scully, S. Hensley, Lifetime prediction for organic coatings on steel and a magnesium alloy using electrochemical impedance methods, Corrosion 50(9) (1994) 705-716. ##[96] S. Pandey, S.B. Mishra, Sol–gel derived organic–inorganic hybrid materials: synthesis, characterizations and applications, Journal of sol-gel science and technology 59(1) (2011) 73-94. ##[97] M. Faustini, L. Nicole, E. Ruiz‐Hitzky, C. Sanchez, History of organic–inorganic hybrid materials: prehistory, art, science, and advanced applications, Advanced Functional Materials 28(27) (2018) 1704158. ##[98] R. Zandi-Zand, A. Ershad-Langroudi, A. Rahimi, Organic–inorganic hybrid coatings for corrosion protection of 1050 aluminum alloy, Journal of Non-Crystalline Solids 351(14-15) (2005) 1307-1311. ##[99] F. García-Galván, M. Mezour, G. Hickman, I. Soliman, A. Jiménez-Morales, V. Barranco, J. Galván, C. Perry, Organic-inorganic hybrid coatings containing phosphorus precursors prepared by sol–gel on Ti6Al4V alloy: Electrochemical and in-vitro biocompatibility evaluation, Progress in Organic Coatings 148 (2020) 105834. ##[100] N. Farhadyar, A. Rahimi, A. Ershad Langroudi, Synthesis and chracterization of inorganic-organic hybrid produced from tetraethoxysilane and epoxy-aromatic amine, IUPAC World Polymer Congress Macro, 2004, p. 2. ##[101] Z.R. ZANDI, L.A. ERSHAD, A. RAHIMI, Improvement of corrosion resistance of organic-inorganic hybrid coatings based on epoxy-silica via aromatic diol curing agent, (2005). ##[102] C. Sanchez, B. Julián, P. Belleville, M. Popall, Applications of hybrid organic–inorganic nanocomposites, Journal of Materials Chemistry 15(35-36) (2005) 3559-3592. ##[103] J.C.B. Alcázar, R.M.J. Lemos, M.C.M. Conde, L.A. Chisini, M.M.S. Salas, B.S. Noremberg, F.V. da Motta, F.F. Demarco, S.B.C. Tarquinio, N.L.V. Carreño, Preparation, characterization, and biocompatibility of different metal oxide/PEG-based hybrid coating synthesized by sol–gel dip coating method for surface modification of titanium, Progress in Organic Coatings 130 (2019) 206-213. ##[104] M. Masudi, A. Rahimi, R.P. Astaneh, Synthesis, Characterization, and Investigation of Inhibitor Release of the Anticorrosion Sol–Gel Hybrid Nanocomposite Coatings, Protection of Metals and Physical Chemistry of Surfaces 55(2) (2019) 363-370. ##[105] Z.R. Zandi, L.A. ERSHAD, A. Rahimi, Synthesis and characterization of nano-composite hybrid coatings based on 3-glycidoxypropyl-trimethoxysilane and bisphenol A, (2005). ##[106] M. Ochi, R. Takahashi, Phase structure and thermomechanical properties of primary and tertiary amine‐cured epoxy/silica hybrids, Journal of Polymer Science Part B: Polymer Physics 39(11) (2001) 1071-1084. ##[107] Y. Ma, L. Chen, Y. Ye, H. Wan, H. Zhou, J. Chen, Preparation and tribological behaviors of a novel organic-inorganic hybrid resin bonded solid lubricating coating cured by ultraviolet radiation, Progress in Organic Coatings 127 (2019) 348-358. ##[108] S. Amiri, A. Rahimi, Hybrid nanocomposite coating by sol–gel method: A review, Iranian Polymer Journal 25(6) (2016) 559-577. ##[109] C.L. Chiang, C.C.M. Ma, D.L. Wu, H.C. Kuan, Preparation, characterization, and properties of novolac‐type phenolic/SiO2 hybrid organic–inorganic nanocomposite materials by sol–gel method, Journal of Polymer Science Part A: Polymer Chemistry 41(7) (2003) 905-913. ##[110] D. Balgude, A. Sabnis, Sol–gel derived hybrid coatings as an environment friendly surface treatment for corrosion protection of metals and their alloys, Journal of sol-gel science and technology 64(1) (2012) 124-134. ##[111] X. Li, Z. Weng, W. Yuan, X. Luo, H.M. Wong, X. Liu, S. Wu, K.W.K. Yeung, Y. Zheng, P.K. Chu, Corrosion resistance of dicalcium phosphate dihydrate/poly(lactic-co-glycolic acid) hybrid coating on AZ31 magnesium alloy, Corrosion Science 102 (2016) 209-221. ##[112] F. Gao, C. Xu, H. Hu, Q. Wang, Y. Gao, H. Chen, Q. Guo, D. Chen, D. Eder, Biomimetic synthesis and characterization of hydroxyapatite/graphene oxide hybrid coating on Mg alloy with enhanced corrosion resistance, Materials Letters 138 (2015) 25-28. ##[113] R.N. Peres, E.S.F. Cardoso, M.F. Montemor, H.G. de Melo, A.V. Benedetti, P.H. Suegama, Influence of the addition of SiO2 nanoparticles to a hybrid coating applied on an AZ31 alloy for early corrosion protection, Surface and Coatings Technology 303 (2016) 372-384. ##[114] S.V. Lamaka, M.F. Montemor, A.F. Galio, M.L. Zheludkevich, C. Trindade, L.F. Dick, M.G.S. Ferreira, Novel hybrid sol–gel coatings for corrosion protection of AZ31B magnesium alloy, Electrochimica Acta 53(14) (2008) 4773-4783. ##[115] M. Zhang, S. Cai, S. Shen, G. Xu, Y. Li, R. Ling, X. Wu, In-situ defect repairing in hydroxyapatite/phytic acid hybrid coatings on AZ31 magnesium alloy by hydrothermal treatment, Journal of Alloys and Compounds 658 (2016) 649-656. ##[116] M.-H. Kang, T.-S. Jang, H.-D. Jung, S.-M. Kim, H.-E. Kim, Y.-H. Koh, J. Song, Poly (ether imide)-silica hybrid coatings for tunable corrosion behavior and improved biocompatibility of magnesium implants, Biomedical Materials 11(3) (2016) 035003. ##[117] F. Pan, X. Yang, D. Zhang, Chemical nature of phytic acid conversion coating on AZ61 magnesium alloy, Applied Surface Science 255(20) (2009) 8363-8371. ##[118] D. Hawake, D. Albright, Metal Finishing, October l995 (1995) 34-38. ##[119] H. Umehara, M. Takaya, Y. Kojima, An investigation of the structure and corrosion resistance of permanganate conversion coatings on AZ91D magnesium alloy, Materials Transactions 42(8) (2001) 1691-1699. ##[120] M. Gonzalez-Nunez, P. Skeldon, G. Thompson, H. Karimzadeh, Kinetics of the development of a nonchromate conversion coating for magnesium alloys and magnesium-based metal matrix composites, Corrosion 55(12) (1999) 1136-1143. ##[121] M. Gonzalez-Nunez, C. Nunez-Lopez, P. Skeldon, G. Thompson, H. Karimzadeh, P. Lyon, T. Wilks, A non-chromate conversion coating for magnesium alloys and magnesium-based metal matrix composites, Corrosion Science 37(11) (1995) 1763-1772. ##[122] A. Simaranov, A. Marshakov, Y. Mikhailovskii, Formation of Conversion Coatings on Magnesium in Moderately Acidic Chromate Solutions, Zashch. Met. 25(5) (1989) 766-774. ##[123] S. Ono, K. Asami, N. Masuko, Mechanism of chemical conversion coating film growth on magnesium and magnesium alloys, Materials transactions 42(7) (2001) 1225-1231. ##[124] C. Lin, C. Lee, W. Li, Y. Chen, G. Fang, Formation of phosphate/permanganate conversion coating on AZ31 magnesium alloy, Journal of The Electrochemical Society 153(3) (2006) B90. ##[125] W. Zhou, D. Shan, E.-H. Han, W. Ke, Structure and formation mechanism of phosphate conversion coating on die-cast AZ91D magnesium alloy, Corrosion Science 50(2) (2008) 329-337. ##[126] Y. Song, D. Shan, R. Chen, F. Zhang, E.-H. Han, Biodegradable behaviors of AZ31 magnesium alloy in simulated body fluid, Materials Science and Engineering: C 29(3) (2009) 1039-1045. ##[127] A.L. Rudd, C.B. Breslin, F. Mansfeld, The corrosion protection afforded by rare earth conversion coatings applied to magnesium, Corrosion Science 42(2) (2000) 275-288. ##[128] M. Dabala, K. Brunelli, E. Napolitani, M. Magrini, Cerium-based chemical conversion coating on AZ63 magnesium alloy, Surface and Coatings Technology 172(2-3) (2003) 227-232. ##[129] B.R. Fazal, S. Moon, Formation of cerium conversion coatings on AZ31 magnesium alloy, 한국표면공학회지 49(1) (2016) 1-13. ##[130] Y. Xiang, W. Hu, X. Liu, C. Zhao, W. Ding, A study on surface state during the pretreatment of electroless nickel plating on magnesium alloys, Transactions of the IMF 79(1) (2001) 27-29. ##[131] K. Brunelli, M. Dabalà, I. Calliari, M. Magrini, Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys, Corrosion Science 47(4) (2005) 989-1000. ##[132] M.F. Montemor, A.M. Simões, M.J. Carmezim, Characterization of rare-earth conversion films formed on the AZ31 magnesium alloy and its relation with corrosion protection, Applied Surface Science 253(16) (2007) 6922-6931. ##[133] L. Li, J. Lei, S. Yu, Y. Tian, Q. Jiang, F. Pan, Formation and characterization of cerium conversion coatings on magnesium alloy, Journal of Rare Earths 26(3) (2008) 383-387. ##[134] C. Lin, C. Changguo, W. Ningning, W. Jimin, D. Ling, Study of Cerium and Lanthanum Conversion Coatings on AZ63 Magnesium Alloy Surface, Rare Metal Materials and Engineering 44(2) (2015) 333-338. ##[135] M. Laleh, F. Kargar, A.S. Rouhaghdam, Investigation of rare earth sealing of porous micro-arc oxidation coating formed on AZ91D magnesium alloy, Journal of Rare Earths 30(12) (2012) 1293-1297. ##[136] M. Bazli, L. Bazli, R. Rahmani, S. Mansoor, M. Ahmadi, R. Pouriamanesh, Concrete filled FRP–PVC tubular columns used in the construction sector: A review, Journal of Composites and Compounds 2(4) (2020) 155-162. ##[137] L. Bazli, M.H. Bagherian, M. Karrabi, F. Abbassi‐Sourki, H. Azizi, Effect of starch ratio and compatibilization on the viscoelastic behavior of POE/starch blends, Journal of Applied Polymer Science 137(29) (2020) 48877. ##[138] S.O. Omid, Z. Goudarzi, L.M. Kangarshahi, A. Mokhtarzade, F. Bahrami, Self-expanding stents based on shape memory alloys and shape memory polymers, Journal of Composites and Compounds 2(3) (2020) 92-98. ##[139] P. Abasian, M. Radmansouri, M.H. Jouybari, M.V. Ghasemi, A. Mohammadi, M. Irani, F.S. Jazi, Incorporation of magnetic NaX zeolite/DOX into the PLA/chitosan nanofibers for sustained release of doxorubicin against carcinoma cells death in vitro, International journal of biological macromolecules 121 (2019) 398-406. ##[140] L. Bazli, A. Khavandi, M.A. Boutorabi, M. Karrabi, Morphology and viscoelastic behavior of silicone rubber/EPDM/Cloisite 15A nanocomposites based on Maxwell model, Iranian Polymer Journal 25(11) (2016) 907-918. ##[141] L. Bazli, A. Khavandi, M.A. Boutorabi, M. Karrabi, Correlation between viscoelastic behavior and morphology of nanocomposites based on SR/EPDM blends compatibilized by maleic anhydride, Polymer 113 (2017) 156-166. ##[142] S. Pourhashem, F. Saba, J. Duan, A. Rashidi, F. Guan, E.G. Nezhad, B. Hou, Polymer/Inorganic Nanocomposite Coatings with Superior Corrosion Protection Performance: A Review, Journal of Industrial and Engineering Chemistry (2020). ##[143] A. Uriondo, M. Esperon-Miguez, S. Perinpanayagam, The present and future of additive manufacturing in the aerospace sector: A review of important aspects, Proceedings of the Institution of Mechanical Engineers, Part G: Journal of Aerospace Engineering 229(11) (2015) 2132-2147. ##[144] A. Kausar, A review of filled and pristine polycarbonate blends and their applications, Journal of Plastic Film and Sheeting 34(1) (2018) 60-97. ##[145] M. Quaresimin, M. Salviato, M. Zappalorto, Strategies for the assessment of nanocomposite mechanical properties, Composites Part B: Engineering 43(5) (2012) 2290-2297. ##[146] F. Awaja, S. Zhang, M. Tripathi, A. Nikiforov, N. Pugno, Cracks, microcracks and fracture in polymer structures: Formation, detection, autonomic repair, Progress in Materials Science 83 (2016) 536-573. ##[147] A. Kausar, Corrosion prevention prospects of polymeric nanocomposites: A review, Journal of Plastic Film and Sheeting 35(2) (2019) 181-202. ##[148] C. Min, P. Nie, W. Tu, C. Shen, X. Chen, H. Song, Preparation and tribological properties of polyimide/carbon sphere microcomposite films under seawater condition, Tribology International 90 (2015) 175-184. ##[149] A.A. Nazeer, E. Al-Hetlani, M.O. Amin, T. Quiñones-Ruiz, I.K. Lednev, A poly(butyl methacrylate)/graphene oxide/TiO2 nanocomposite coating with superior corrosion protection for AZ31 alloy in chloride solution, Chemical Engineering Journal 361 (2019) 485-498. ##[150] F. Soleymani, R. Emadi, S. Sadeghzade, F. Tavangarian, Applying baghdadite/PCL/chitosan nanocomposite coating on AZ91 magnesium alloy to improve corrosion behavior, bioactivity, and biodegradability, Coatings 9(12) (2019) 789. ##[151] K. Catt, H. Li, X.T. Cui, Poly (3,4-ethylenedioxythiophene) graphene oxide composite coatings for controlling magnesium implant corrosion, Acta Biomaterialia 48 (2017) 530-540. ##[152] N. Rahimi Roshan, H. Hassannejad, A. Nouri, Corrosion and mechanical behaviour of biodegradable PLA-cellulose nanocomposite coating on AZ31 magnesium alloy, Surface Engineering (2020) 1-10. ##[153] Y. Zhang, Y. Shao, T. Zhang, G. Meng, F. Wang, High corrosion protection of a polyaniline/organophilic montmorillonite coating for magnesium alloys, Progress in Organic Coatings 76(5) (2013) 804-811. ##[154] B.-D. Hahn, D.-S. Park, J.-J. Choi, J. Ryu, W.-H. Yoon, J.-H. Choi, H.-E. Kim, S.-G. Kim, Aerosol deposition of hydroxyapatite–chitosan composite coatings on biodegradable magnesium alloy, Surface and Coatings Technology 205(8) (2011) 3112-3118. ##[155] I. Johnson, K. Akari, H. Liu, Nanostructured hydroxyapatite/poly(lactic-co-glycolic acid) composite coating for controlling magnesium degradation in simulated body fluid, Nanotechnology 24(37) (2013) 375103. ##[156] Y. Wang, N. Yamada, J. Xu, J. Zhang, Q. Chen, Y. Ootani, Y. Higuchi, N. Ozawa, M.-I.D.B. Bouchet, J.M. Martin, Triboemission of hydrocarbon molecules from diamond-like carbon friction interface induces atomic-scale wear, Science advances 5(11) (2019) eaax9301. ##[157] H. Yoshinaka, S. Inubushi, T. Wakita, T. Yokoya, Y. Muraoka, Formation of Q-carbon by adjusting sp3 content in diamond-like carbon films and laser energy density of pulsed laser annealing, Carbon 167 (2020) 504-511. ##[158] Z. Ren, H. Qin, Y. Dong, G. Doll, C. Ye, A boron-doped diamond like carbon coating with high hardness and low friction coefficient, Wear 436 (2019) 203031. ##[159] Y. Lei, J. Jiang, Y. Wang, T. Bi, L. Zhang, Structure evolution and stress transition in diamond-like carbon films by glancing angle deposition, Applied Surface Science 479 (2019) 12-19. ##[160] A. Moreno-Bárcenas, J. Alvarado-Orozco, J.G. Carmona, G. Mondragón-Rodríguez, J. González-Hernández, A. García-García, Synergistic effect of plasma nitriding and bias voltage on the adhesion of diamond-like carbon coatings on M2 steel by PECVD, Surface and Coatings Technology 374 (2019) 327-337. ##[161] N. Konkhunthot, P. Photongkam, P. Wongpanya, Improvement of thermal stability, adhesion strength and corrosion performance of diamond-like carbon films with titanium doping, Applied Surface Science 469 (2019) 471-486. ##[162] C.A. Love, R.B. Cook, T.J. Harvey, P.A. Dearnley, R.J.K. Wood, Diamond like carbon coatings for potential application in biological implants—a review, Tribology International 63 (2013) 141-150. ##[163] A. Mazare, A. Anghel, C. Surdu-Bob, G. Totea, I. Demetrescu, D. Ionita, Silver doped diamond-like carbon antibacterial and corrosion resistance coatings on titanium, Thin Solid Films 657 (2018) 16-23. ##[164] G. Wu, W. Dai, H. Zheng, A. Wang, Improving wear resistance and corrosion resistance of AZ31 magnesium alloy by DLC/AlN/Al coating, Surface and Coatings Technology 205(7) (2010) 2067-2073. ##[165] Y.L. Wei, L.L. Huang, L.J. Han, Y.S. Chen, Corrosion resistance and surface biocompatibility of diamond-like carbon coating on AZ31D magnesium alloy, International Journal of Surface Science and Engineering 10(2) (2016) 101-115. ##[166] C.-M. Ning, X.-J. Cui, L.-L. Shang, Y.-J. Zhang, G.-A. Zhang, Structure and properties of different elements doped diamond-like carbon on micro-arc oxidation coated AZ31B Mg alloy, Diamond and Related Materials (2020) 107832. ##[167] G. Wu, L. Sun, W. Dai, L. Song, A. Wang, Influence of interlayers on corrosion resistance of diamond-like carbon coating on magnesium alloy, Surface and Coatings Technology 204(14) (2010) 2193-2196. ##[168] I. Masami, N. Setsuo, S. Tsutomu, C. Junho, Improvement of corrosion protection property of Mg-alloy by DLC and Si–DLC coatings with PBII technique and multi-target DC–RF magnetron sputtering, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 267(8) (2009) 1675-1679. ##[169] Y. Uematsu, T. Kakiuchi, T. Teratani, Y. Harada, K. Tokaji, Improvement of corrosion fatigue strength of magnesium alloy by multilayer diamond-like carbon coatings, Surface and Coatings Technology 205(8) (2011) 2778-2784. ##[170] N. Yamauchi, N. Ueda, A. Okamoto, T. Sone, M. Tsujikawa, S. Oki, DLC coating on Mg–Li alloy, Surface and Coatings Technology 201(9) (2007) 4913-4918.