﻿<?xml version="1.0" encoding="utf-8" ?>
<XML>
  <ISCJOURNAL>   
    <YEAR>2020</YEAR>
    <VOL>2</VOL>
    <NO>3</NO>
    <MOSALSAL>3</MOSALSAL>
    <PAGE_NO>7</PAGE_NO> 
    <ARTICLES>
      <ARTICLE> 
        <LANGUAGE_ID>1</LANGUAGE_ID>					
        <TitleF/>
        <TitleE>Clay-reinforced nanocomposites for the slow release of chemical fertilizers and water retention</TitleE> 
        <URL>https://jourcc.com/index.php/jourcc/article/view/jcc224</URL>
        <DOI>10.29252/jcc.2.2.4</DOI>
        <DOR>20.1001.1.26765837.2020.2.3.4.4</DOR>		
        <ABSTRACTS>
          <ABSTRACT>         
            <LANGUAGE_ID>1</LANGUAGE_ID>          
            <CONTENT>The present study includes an overview of the applications of clay-based nanocomposites over the past decade to date in various fields such as pharmaceuticals, water treatment, food packaging, electricity, automotive, and especially the production of chemical fertilizers with water retention and slow release. In the agricultural area, one of the promising materials that help green chemical engineering and green chemistry is slow-release fertilizer (SRF). Clay minerals and also clay nanocomposites provide cost-effective and efficient material for this purpose. In this paper, the research and development of polymer nanocomposites based on clay in recent years with the focus on their application as novel fertilizers have been reviewed. Clay minerals are promising reinforcements to manufacture high-performance, lightweight, and low-cost nanocomposites because of their abundance, layered structure, low cost, and rich intercalation chemistry.</CONTENT>
          </ABSTRACT>
         </ABSTRACTS>
        <PAGES>
          <PAGE>
            <FPAGE>85</FPAGE>
            <TPAGE>91</TPAGE>
          </PAGE>
        </PAGES>
        <AUTHORS>
          <AUTHOR>           
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Aliasghar</NameE>
            <MidNameE/>		
            <FamilyE>Abuchenari</FamilyE>
            <Organizations>
              <Organization>Shahid Bahonar University</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>aliab596@yahoo.com</Email>
            </EMAILS>
          </AUTHOR>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Khatereh</NameE>
            <MidNameE/>		
            <FamilyE>Hardani</FamilyE>
            <Organizations>
              <Organization>Khorramshahr University of Marine Science and Technology</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>info@jourcc.com</Email>		
            </EMAILS>
          </AUTHOR>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Somayeh</NameE>
            <MidNameE/>		
            <FamilyE>Abazari</FamilyE>
            <Organizations>
              <Organization>Amirkabir University on Technology</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>info@jourcc.com</Email>		
            </EMAILS>
          </AUTHOR>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Fahimeh</NameE>
            <MidNameE/>		
            <FamilyE>Naghdi</FamilyE>
            <Organizations>
              <Organization>Babol Noshirvani University of Technology</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>info@jourcc.com</Email>		
            </EMAILS>
          </AUTHOR>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Mehdy</NameE>
            <MidNameE/>		
            <FamilyE>Ahmady Keleshteri</FamilyE>
            <Organizations>
              <Organization>Najafabad Branch, Islamic Azad University (IAU)</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>info@jourcc.com</Email>		
            </EMAILS>
          </AUTHOR>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Ata</NameE>
            <MidNameE/>		
            <FamilyE>Jamavari</FamilyE>
            <Organizations>
              <Organization>Iran University of Science and Technology</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>info@jourcc.com</Email>		
            </EMAILS>
          </AUTHOR>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Amir</NameE>
            <MidNameE/>		
            <FamilyE>Modarresi Chahardehi</FamilyE>
            <Organizations>
              <Organization>Universiti Sains Malaysia</Organization>
            </Organizations>
            <Countries>
              <Country>Malaysia</Country>
            </Countries>
            <EMAILS>
              <Email>info@jourcc.com</Email>		
            </EMAILS>
          </AUTHOR>
        </AUTHORS>
        <KEYWORDS>
          <KEYWORD>
            <KeyText>Clay nanocomposites</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Slow release</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Controlled release</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Fertilizer</KeyText>
          </KEYWORD>
        </KEYWORDS>
        <PDFFileName>Article4.pdf</PDFFileName>
		<REFRENCES>
          <REFRENCE>  		  
            <REF>[1] B. Ni, M. Liu, S. Lü, Multifunctional slow-release urea fertilizer from ethylcellulose and superabsorbent coated formulations, Chemical Engineering Journal 155(3) (2009) 892-898.##[2] W. Wang, A. Wang, Synthe-sis, swelling behaviors, and slow‐release characteristics of a guar gum‐g‐poly (sodium acrylate)/sodium hu-mate superabsorbent, Journal of Applied polymer science 112(4) (2009) 2102-2111.##[3] S. Al-Zahrani, Utili-zation of polyethylene and paraffin waxes as controlled delivery systems for different fertilizers, Industrial and engineering chemistry research 39(2) (2000) 367-371.##[4] R. Parish, Effect of coating thickness on spreader damage to encapsulated controlled-release fertilizer granules, Applied Engineering in Agriculture 17(4) (2001) 459.##[5] A. Pakseresht, A. Javadi, E. Ghasali, A. Shahbazkhan, S. Shakhesi, Evaluation of hot corrosion behavior of plasma sprayed thermal barrier coatings with graded intermediate layer and double ce-ramic top layer, Surface and Coatings Technology 288 (2016) 36-45.##[6] A. Giroto, S. Fidélis, C. Ribeiro, Controlled release from hydroxyapatite nanoparticles incorporated into biodegradable, soluble host matrixes, Rsc Advances 5(126) (2015) 104179-104186.##[7] U. Shavit, M. Reiss, A. Shaviv, Wetting mechanisms of gel-based controlled-release fertilizers, Journal of Controlled Release 88(1) (2003) 71-83.##[8] S. Saadi, B. Nazari, Submission Title: Recent Developments and Applications of Nanocomposites in Solar Cells: a Re-view, Composites and Compounds 1(1) (2019).##[9] S.S. Ray, M. Okamoto, New polylactide/layered silicate nanocomposites, 6 melt rheology and foam processing, Macromolecular materials and engineering (288; NUMB 12) (2003) 936-944.##[10] Q. Zeng, A. Yu, G. Lu, D.R. Paul, Clay-based polymer nanocomposites: research and commercial development, Journal of nanoscience and nanotechnology 5(10) (2005) 1574-1592.##[11] P.C. LeBaron, Z. Wang, T.J. Pinnavaia, Polymer-layered silicate nanocomposites: an overview, Applied clay science 15(1-2) (1999) 11-29.##[12] T.J. Pinnavaia, G.W. Beall, Polymer-clay nanocomposites, John Wiley2000.##[13] C. Kannan, R. Ramanujam, Comparative study on the mechanical and microstructural characterisation of AA 7075 nano and hybrid nanocomposites produced by stir and squeeze casting, Journal of advanced research 8(4) (2017) 309-319.##[14] R. Singh, V. Mahto, Synthesis, characterization and evaluation of polyacrylamide graft starch/clay nanocomposite hydrogel system for enhanced oil recovery, Petroleum Science 14(4) (2017) 765-779.##[15] M. Mousa, N.D. Evans, R.O. Oreffo, J.I. Dawson, Clay nanoparticles for regenerative medicine and biomaterial design: a review of clay bioactivity, Biomaterials 159 (2018) 204-214.##[16] S. Wu, A. Cheng, H. Hua, J. Shen, A study on structure and mechanical properties of polyure-thane/organic-montmorillonite nanocomposites, Polymer-Plastics Technology and Engineering 45(6) (2006) 685-689.##[17] W. Chow, J. Teoh, L. Lim, Mechanical and hygrothermal aging study on polystyrene/organo-montmorillonite nanocomposites, Polymer-Plastics Technology and Engineering 47(10) (2008) 1040-1045.##[18] S.C. Tjong, Structural and mechanical properties of polymer nanocomposites, Materials Science and Engineering: R: Reports 53(3-4) (2006) 73-197.##[19] S. Pavlidou, C. Papaspyrides, A review on poly-mer–layered silicate nanocomposites, Progress in polymer science 33(12) (2008) 1119-1198.##[20] G. Sposi-to, N.T. Skipper, R. Sutton, S.-h. Park, A.K. Soper, J.A. Greathouse, Surface geochemistry of the clay miner-als, Proceedings of the National Academy of Sciences 96(7) (1999) 3358-3364.##[21] M. Alexandre, P. Du-bois, Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials, Materials Science and Engineering: R: Reports 28(1-2) (2000) 1-63.##[22] L. Bazli, A. Khavandi, M.A. Bou-torabi, M. Karrabi, Correlation between viscoelastic behavior and morphology of nanocomposites based on SR/EPDM blends compatibilized by maleic anhydride, Polymer 113 (2017) 156-166.##[23] G. Madhumitha, J. Fowsiya, S. Mohana Roopan, V.K. Thakur, Recent advances in starch–clay nanocomposites, International Journal of Polymer Analysis and Characterization 23(4) (2018) 331-345.##[24] J.M. Garces, D.J. Moll, J. Bicerano, R. Fibiger, D.G. McLeod, Polymeric nanocomposites for automotive applications, Advanced Mate-rials 12(23) (2000) 1835-1839.##[25] A.C. Lima, L.M. Jou, O.E. Barcia, I.C. Margarit-Mattos, Montmorillo-nite as corrosion protective pigment, Corrosion Science 141 (2018) 182-194.##[26] A.M. Youssef, S.M. El-Sayed, Bionanocomposites materials for food packaging applications: Concepts and future outlook, Carbohy-drate polymers 193 (2018) 19-27.##[27] E. Asadi, A. Fassadi Chimeh, S. Hosseini, S. Rahimi, B. Sarkhosh, L. Bazli, R. Bashiri, A.H. Vakili Tahmorsati, A Review of Clinical Applications of Graphene Quantum Dot-based Composites, Composites and Compounds 1(1) (2019).##[28] W. Paul, C.P. Sharma, Inorganic nanopar-ticles for targeted drug delivery, Biointegration of Medical Implant Materials, Elsevier2020, pp. 333-373.##[29] J.-H. Chang, Y.U. An, D. Cho, E.P. Giannelis, Poly (lactic acid) nanocomposites: comparison of their properties with montmorillonite and synthetic mica (II), Polymer 44(13) (2003) 3715-3720.##[30] S.H. Cypes, W.M. Saltzman, E.P. Giannelis, Organosilicate-polymer drug delivery systems: controlled release and enhanced mechanical properties, Journal of controlled release 90(2) (2003) 163-169.##[31] A. Kiersnowski, J. Pigłowski, Polymer-layered silicate nanocomposites based on poly (ε-caprolactone), European polymer jour-nal 40(6) (2004) 1199-1207.##[32] E. Günister, D. Pestreli, C.H. Ünlü, O. Atıcı, N. Güngör, Synthesis and characterization of chitosan-MMT biocomposite systems, Carbohydrate Polymers 67(3) (2007) 358-365.##[33] C. Pérez, V. Alvarez, A. Vazquez, Creep behaviour of layered silicate/starch–polycaprolactone blends nanocomposites, Materials Science and Engineering: A 480(1-2) (2008) 259-265.##[34] Y. Rao, Gela-tin–clay nanocomposites of improved properties, Polymer 48(18) (2007) 5369-5375.##[35] M.-Y. Chang, R.-S. Juang, Stability and catalytic kinetics of acid phosphatase immobilized on composite beads of chitosan and activated clay, Process Biochemistry 39(9) (2004) 1087-1091.##[36] M.-Y. Chang, R.-S. Juang, Use of chi-tosan–clay composite as immobilization support for improved activity and stability of β-glucosidase, Bio-chemical Engineering Journal 35(1) (2007) 93-98.##[37] M.-Y. Chang, H.-C. Kao, R.-S. Juang, Thermal inac-tivation and reactivity of β-glucosidase immobilized on chitosan–clay composite, International journal of bio-logical macromolecules 43(1) (2008) 48-53.##[38] V.B. Yadav, R. Gadi, S. Kalra, Clay based nanocomposites for removal of heavy metals from water: A review, Journal of Environmental Management 232 (2019) 803-817.##[39] E.I. Unuabonah, A. Taubert, Clay–polymer nanocomposites (CPNs): Adsorbents of the future for water treatment, Applied Clay Science 99 (2014) 83-92.##[40] S.A. Hosseini, M. Vossoughi, N.M. Mahmoodi, M. Sadrzadeh, Clay-based electrospun nanofibrous membranes for colored wastewater treatment, Applied Clay Science 168 (2019) 77-86.##[41] M.E. Trenkel, Slow-and controlled-release and stabilized fertilizers: An option for enhancing nutrient use efficiency in agriculture, IFA, International fertilizer industry associa-tion2010.##[42] M. Sultan, A. Abdelhakim, M. Nassar, Cellulose-Based Hydrogels as Smart, Green and Con-trollable Nitrogenous Fertilizers Releasing Agents, Journal of Testing and Evaluation 49(4) (2019).##[43] B. Zhao, S. Dong, J. Zhang, P. Liu, Effects of controlled-release fertiliser on nitrogen use efficiency in summer maize, PloS one 8(8) (2013).##[44] J. Li, X. Zhuang, O. Font, N. Moreno, V.R. Vallejo, X. Querol, A. Tobias, Synthesis of merlinoite from Chinese coal fly ashes and its potential utilization as slow release K-fertilizer, Journal of hazardous materials 265 (2014) 242-252.##[45] A. Bortolin, F.A. Aouada, L.H. Mattoso, C. Ribei-ro, Nanocomposite PAAm/methyl cellulose/montmorillonite hydrogel: evidence of synergistic effects for the slow release of fertilizers, Journal of agricultural and food chemistry 61(31) (2013) 7431-7439.##[46] L. Ba-zli, M.H. Bagherian, M. Karrabi, F. Abbassi‐Sourki, H. Azizi, Effect of starch ratio and compatibilization on the viscoelastic behavior of POE/starch blends, Journal of Applied Polymer Science  (2019) 48877.##[47] T.S. Daitx, M. Giovanela, L.N. Carli, R.S. Mauler, Biodegradable polymer/clay systems for highly controlled re-lease of NPK fertilizer, Polymers for Advanced Technologies 30(3) (2019) 631-639.##[48] K. Yano, A. Usuki, A. Okada, T. Kurauchi, O. Kamigaito, Polymer Science Part A, Polymer Chemistry 31 (1993) 2493.##[49] R. Bharadwaj, A. Mehrabi, C. Hamilton, C. Trujillo, M. Murga, R. Fan, A. Chavira, A. Thompson, Structure–property relationships in cross-linked polyester–clay nanocomposites, Polymer 43(13) (2002) 3699-3705.##[50] N. Sheng, M.C. Boyce, D.M. Parks, G. Rutledge, J. Abes, R. Cohen, Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle, Polymer 45(2) (2004) 487-506.##[51] C. Thellen, C. Orroth, D. Froio, D. Ziegler, J. Lucciarini, R. Farrell, N.A. D’Souza, J.A. Ratto, In-fluence of montmorillonite layered silicate on plasticized poly (l-lactide) blown films, Polymer 46(25) (2005) 11716-11727.##[52] L. Bazli, A. Khavandi, M.A. Boutorabi, M. Karrabi, Morphology and viscoelastic behav-ior of silicone rubber/EPDM/Cloisite 15A nanocomposites based on Maxwell model, Iranian Polymer Journal 25(11) (2016) 907-918.##[53] N. Xiaoyu, W. Yuejin, W. Zhengyan, W. Lin, Q. Guannan, Y. Lixiang, A novel slow-release urea fertiliser: Physical and chemical analysis of its structure and study of its release mecha-nism, Biosystems engineering 115(3) (2013) 274-282.##[54] M. Rinaudo, Chitin and chitosan: properties and applications, Progress in polymer science 31(7) (2006) 603-632.##[55] Q. Li, E. Dunn, E. Grandmaison, M.F. Goosen, Applications and properties of chitosan, Journal of Bioactive and Compatible Polymers 7(4) (1992) 370-397.##[56] K. Haraguchi, Nanocomposite hydrogels, Current Opinion in Solid State and Materials Sci-ence 11(3-4) (2007) 47-54.##[57] X. Wang, S. Lü, C. Gao, X. Xu, Y. Wei, X. Bai, C. Feng, N. Gao, M. Liu, L. Wu, Biomass-based multifunctional fertilizer system featuring controlled-release nutrient, water-retention and amelioration of soil, RSC advances 4(35) (2014) 18382-18390.##[58] K. Xing, X. Zhu, X. Peng, S. Qin, Chitosan antimicrobial and eliciting properties for pest control in agriculture: a review, Agronomy for Sus-tainable Development 35(2) (2015) 569-588.##[59] J.J. Perez, N.J. Francois, Chitosan-starch beads prepared by ionotropic gelation as potential matrices for controlled release of fertilizers, Carbohydrate polymers 148 (2016) 134-142.##[60] D.Y. Wu, S. Meure, D. Solomon, Self-healing polymeric materials: a review of recent developments, Progress in polymer science 33(5) (2008) 479-522.##[61] B.R. dos Santos, F.B. Bacalhau, T. dos Santos Pereira, C.F. Souza, R. Faez, Chitosan-montmorillonite microspheres: a sustainable fertilizer de-livery system, Carbohydrate polymers 127 (2015) 340-346.##[62] C.F. Souza, R. Faez, F.B. Bacalhau, M.F. Bacarin, T.S. Pereira, In situ monitoring of a controlled release of fertilizers in lettuce crop, Engenharia Agrícola 37(4) (2017) 656-664.##[63] L.L. Messa, C.F. Souza, R. Faez, Spray-dried potassium nitrate-containing chitosan/montmorillonite microparticles as potential enhanced efficiency fertilizer, Polymer Test-ing 81 (2020) 106196.##[64] M. George, T.E. Abraham, Polyionic hydrocolloids for the intestinal delivery of protein drugs: alginate and chitosan—a review, Journal of controlled release 114(1) (2006) 1-14.##[65] Z. Wu, Y. Zhao, I. Kaleem, C. Li, Preparation of calcium–alginate microcapsuled microbial fertilizer coating Klebsiella oxytoca Rs-5 and its performance under salinity stress, European journal of soil biology 47(2) (2011) 152-159.##[66] A.L. Córdoba, L. Deladino, M. Martino, Effect of starch filler on calcium-alginate hy-drogels loaded with yerba mate antioxidants, Carbohydrate polymers 95(1) (2013) 315-323.##[67] Y. He, Z. Wu, L. Tu, Y. Han, G. Zhang, C. Li, Encapsulation and characterization of slow-release microbial fertilizer from the composites of bentonite and alginate, Applied Clay Science 109 (2015) 68-75.##[68] B. Singh, D. Sharma, R. Kumar, A. Gupta, Controlled release of the fungicide thiram from starch–alginate–clay based for-mulation, Applied Clay Science 45(1-2) (2009) 76-82.##[69] D. Klemm, B. Heublein, H.P. Fink, A. Bohn, Cellulose: fascinating biopolymer and sustainable raw material, Angewandte chemie international edition 44(22) (2005) 3358-3393.##[70] I. Siró, D. Plackett, Microfibrillated cellulose and new nanocomposite mate-rials: a review, Cellulose 17(3) (2010) 459-494.##[71] D. Davidson, F.X. Gu, Materials for sustained and con-trolled release of nutrients and molecules to support plant growth, Journal of agricultural and food chemistry 60(4) (2012) 870-876.##[72] S. Bajpai, M. Swarnkar, S. Ahuja, On-demand release of urea from a cellulosic hydrogel using a sprinkler based irrigation (SBI) model, Journal of Macromolecular Science, Part A 52(10) (2015) 779-785.##[73] H. Li, Y. Zhou, W. Tu, J. Ye, Z. Zou, State‐of‐the‐art progress in diverse heterostruc-tured photocatalysts toward promoting photocatalytic performance, Advanced Functional Materials 25(7) (2015) 998-1013.##[74] H.A. Essawy, M.B. Ghazy, F.A. El-Hai, M.F. Mohamed, Superabsorbent hydrogels via graft polymerization of acrylic acid from chitosan-cellulose hybrid and their potential in controlled re-lease of soil nutrients, International journal of biological macromolecules 89 (2016) 144-151.##[75] M. Fer-nández‐Pérez, F. Garrido‐Herrera, E. González‐Pradas, M. Villafranca‐Sánchez, F. Flores‐Céspedes, Lignin and ethylcellulose as polymers in controlled release formulations of urea, Journal of applied polymer science 108(6) (2008) 3796-3803.##[76] B. Ni, M. Liu, S. Lu, L. Xie, Y. Wang, Environmentally friendly slow-release nitrogen fertilizer, Journal of agricultural and food chemistry 59(18) (2011) 10169-10175.##[77] B. Ni, M. Liu, S. Lü, L. Xie, Y. Wang, Multifunctional slow-release organic− inorganic compound fertilizer, Journal of agricultural and food chemistry 58(23) (2010) 12373-12378.##[78] Y. Verma, S. Datta, I.K. Mandal, D. Sarkar, Effect of phosphorus loaded organically modified nanoclay-polymer composite on release and fixation of phosphorus and its uptake by wheat (Triticum aestivum L.), Journal of Pure and Applied Microbiology 10(3) (2016) 2299-2306.##[79] A. Rashidzadeh, A. Olad, Slow-released NPK fertilizer encapsulated by NaAlg-g-poly (AA-co-AAm)/MMT superabsorbent nanocomposite, Carbohydrate polymers 114 (2014) 269-278.##[80] Y.D. Noh, S. Komarneni, M. Park, Mineral-based slow release fertilizers: a review, Korean Journal of Soil Science and Fertilizer 48(1) (2015) 1-7.</REF>
          </REFRENCE>
        </REFRENCES>

      </ARTICLE>
    </ARTICLES>
  </ISCJOURNAL>
</XML>
