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  <ISCJOURNAL>
    <YEAR>2025</YEAR>
    <VOL>7</VOL>
    <NO>23</NO>
    <MOSALSAL>23</MOSALSAL>
    <PAGE_NO>5</PAGE_NO>
    <ARTICLES>
      <DOI>10.61882/jcc.7.2.5</DOI>      
      <ARTICLE>
        <LANGUAGE_ID>1</LANGUAGE_ID>
        <TitleF/>
        <TitleE>Corrosion behavior modeling and Montel Carlo simulation of a biomedical Ti–Zr–Nb–Ta alloy for dental applications</TitleE>      
        <ABSTRACTS>
          <ABSTRACT>
            <LANGUAGE_ID>1</LANGUAGE_ID>
            <CONTENT>The potentiodynamic polarization behavior of as-cast and accumulative roll-bonded (ARB) Ti–10Zr–5Nb–5Ta alloys was investigated in neutral Ringer solution at 37 °C to assess the influence of microstructural refinement on corrosion resistance and passivation. Using the Tafel equation, the potentiodynamic behavior of the as-cast and ARB-processed alloys was modeled to quantify electrochemical performance, with results indicating that ARB processing significantly modifies passive film characteristics. Model predictions were compared with experimental data, showing good agreement. The models were then coupled with Monte Carlo simulation to account for uncertainties in experimental data and fitting parameters, enabling probabilistic predictions of corrosion behavior. This integrated approach provides a robust evaluation of variability and reliability in electrochemical performance, offering a comprehensive assessment of the alloy’s stability in physiological environments. The findings demonstrate that ARB processing can enhance corrosion resistance, supporting its potential for the development of durable titanium-based biomaterials for demanding biomedical and dental applications.</CONTENT>
            </ABSTRACT>
        </ABSTRACTS>
        <PAGES>
          <PAGE>
            <FPAGE>1</FPAGE>
            <TPAGE>5</TPAGE>
          </PAGE>
        </PAGES>
        <AUTHORS>
          <AUTHOR>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Tahereh</NameE>
            <MidNameE/>
            <FamilyE>Mahmoudi Alashti</FamilyE>
            <Organizations>
              <Organization>Department of Medical Engineering, Islamic Azad University,South Tehran Branch, Tehran</Organization>
            </Organizations>
            <Countries>
              <Country>Iran</Country>
            </Countries>
            <EMAILS>
              <Email>mt.mahmoudi1367@gmail.com</Email>
            </EMAILS>
            <Name/>
            <MidName/>
            <Family/>
            <NameE>Ketevan</NameE>
            <MidNameE/>
            <FamilyE>Mikeladze</FamilyE>
            <Organizations>
              <Organization>BAU International University, Batumi  School of Medicine and Health Science</Organization>
            </Organizations>
            <Countries>
              <Country>Georgia</Country>
            </Countries>
            <EMAILS>
              <Email>anukachx@gmail.com</Email>
            </EMAILS>          
          </AUTHOR>
        </AUTHORS>
        <KEYWORDS>
          <KEYWORD>
            <KeyText>potentiodynamic polarization behavior</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>As-cast process</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Accumulative roll-bonded process</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Modeling</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Monte Carlo simulation</KeyText>
          </KEYWORD>
          <KEYWORD>
            <KeyText>Dental application</KeyText>                   
          </KEYWORD>
        </KEYWORDS>
        <PDFFileName>2</PDFFileName>
        <REFRENCES>
          <REFRENCE>
            <REF>[1] M. Niinomi, Mechanical biocompatibilities of titanium alloys for biomedical applications, Journal of the mechanical behavior of biomedical materials 1(1) (2008) 30–42.##[2] L. Murr, S. Quinones, S. Gaytan, M. Lopez, A. Rodela, E. Martinez, D. Hernandez, E. Martinez, F. Medina, R. Wicker, Microstructure and mechanical behavior of Ti–6Al–4V produced by rapid-layer manufacturing, for biomedical applications, Journal of the mechanical behavior of biomedical materials 2(1) (2009) 20–32.##[3] M. Khan, R. Williams, D. Williams, In-vitro corrosion and wear of titanium alloys in the biological environment, Biomaterials 17(22) (1996) 2117–2126.##[4] S. Tamilselvi, R. Murugaraj, N. Rajendran, Electrochemical impedance spectroscopic studies of titanium and its alloys in saline medium, Materials and Corrosion 58(2) (2007) 113–120.##[5] A. Guitar, G. Vigna, M. Luppo, Microstructure and tensile properties after thermohydrogen processing of Ti–6Al–4V, Journal of the Mechanical Behavior of Biomedical Materials 2(2) (2009) 156–163.##[6] C. Ramos-Saenz, P. Sundaram, N. Diffoot-Carlo, Tribological properties of Ti-based alloys in a simulated bone–implant interface with Ringer’s solution at fretting contacts, Journal of the mechanical behavior of biomedical materials 3(8) (2010) 549–558.##[7] M. Geetha, A. K. Singh, R. Asokamani, A. K. Gogia, Ti based biomaterials, the ultimate choice for orthopaedic implants–A review, Progress in materials science 54(3) (2009) 397–425.##[8] G. Van der Voet, E. Marani, S. Tio, F. De Wolff, Aluminium neurotoxicity, Progress in histochemistry and cytochemistry 23(1-4) (1991) 235–242.##[9] N. Abavi Torghabeh, R. Pouriamanesh, A review on Ti-based metal matrix composite coatings, Journal of Composites and Compounds 4(13) (2022) 209–219.##[10] M. Reisi Nafchi, R. Ebrahimi-kahrizsangi, Synthesis of Zn-Co-TiO2 nanocomposite coatings by electrodeposition with photocatalytic and antifungal activities, Journal of Composites and Compounds 3(9) (2021) 213–217.##[11] V. P. S. Sidhu, R. Borges, M. Yusuf, S. Mahmoudi, S. F. Ghorbani, M. Hosseinikia, P. Salahshour, F. Sadeghi, M. Arefian, A comprehensive review of bioactive glass: synthesis, ion substitution, application, challenges, and future perspectives, Journal of Composites and Compounds 3(9) (2021) 247–261.##[12] M. F. López, L. Soriano, F. J. Palomares, M. Sánchez‐Agudo, G. Fuentes, A. Gutiérrez, J. A. Jiménez, Soft x‐ray absorption spectroscopy study of oxide layers on titanium alloys, Surface and Interface Analysis: An International Journal devoted to the development and application of techniques for the analysis of surfaces, interfaces and thin films 33(7) (2002) 570–576.##[13] M. F. López, J. A. Jiménez, A. Gutierrez, Corrosion study of surface-modified vanadium-free titanium alloys, Electrochimica Acta 48(10) (2003) 1395–1401.##[14] C. Morant, M. F. López, A. Gutiérrez, J. A. Jiménez, AFM and SEM characterization of non-toxic vanadium-free Ti alloys used as biomaterials, Applied Surface Science 220(1-4) (2003) 79–87.##[15] S. Rao, Y. Okazaki, T. Tateishi, T. Ushida, Y. Ito, Cytocompatibility of new Ti alloy without Al and V by evaluating the relative growth ratios of fibroblasts L929 and osteoblasts MC3T3-E1 cells, Materials Science and Engineering: C 4(4) (1997) 311–314.##[16] S. Yu, J. Scully, Corrosion and passivity of Ti-13% Nb-13% Zr in comparison to other biomedical implant alloys, Corrosion 53(12) (1997) 965–976.##[17] S. L. de Assis, S. Wolynec, I. Costa, Corrosion characterization of titanium alloys by electrochemical techniques, Electrochimica Acta 51(8-9) (2006) 1815–1819.##[18] S. L. d. Assis, I. Costa, Electrochemical evaluation of Ti‐13Nb‐13Zr, Ti‐6Al‐4V and Ti‐6Al‐7Nb alloys for biomedical application by long‐term immersion tests, Materials and Corrosion 58(5) (2007) 329–333.##[19] S. L. d. Assis, S. Wolynec, I. Costa, The electrochemical behaviour of Ti‐13Nb‐13Zr alloy in various solutions, Materials and Corrosion 59(9) (2008) 739–743.##[20] A. Robin, O. Carvalho, S. Schneider, S. Schneider, Corrosion behavior of Ti‐xNb‐13Zr alloys in Ringer's solution, Materials and corrosion 59(12) (2008) 929–933.##[21] P. Thomsen, C. Larsson, L. Ericson, L. Sennerby, J. Lausmaa, B. Kasemo, Structure of the interface between rabbit cortical bone and implants of gold, zirconium and titanium, Journal of Materials Science: Materials in Medicine 8(11) (1997) 653–665.##[22] E. Eisenbarth, D. Velten, M. Müller, R. Thull, J. Breme, Biocompatibility of β-stabilizing elements of titanium alloys, Biomaterials 25(26) (2004) 5705–5713.##[23] B. Wang, Y. Zheng, L. Zhao, Electrochemical corrosion behavior of biomedical Ti–22Nb and Ti–22Nb–6Zr alloys in saline medium, Materials and Corrosion 60(10) (2009) 788–794.##[24] D. Q. Martins, W. R. Osório, M. E. Souza, R. Caram, A. Garcia, Effects of Zr content on microstructure and corrosion resistance of Ti–30Nb–Zr casting alloys for biomedical applications, Electrochimica Acta 53(6) (2008) 2809–2817.##[25] W.-S. Lee, C.-F. Lin, T.-H. Chen, H.-H. Hwang, Effects of strain rate and temperature on mechanical behaviour of Ti–15Mo–5Zr–3Al alloy, Journal of the mechanical behavior of biomedical materials 1(4) (2008) 336–344.##[26] S. Tamilselvi, N. Rajendran, In vitro corrosion behaviour of Ti‐5Al‐2Nb‐1Ta alloy in Hanks solution, Materials and Corrosion 58(4) (2007) 285–289.##[27] Y. Okazaki, A new Ti–15Zr–4Nb–4Ta alloy for medical applications, Current Opinion in Solid State and Materials Science 5(1) (2001) 45–53.##[28] Y. Okazaki, E. Nishimura, H. Nakada, K. Kobayashi, Surface analysis of Ti–15Zr–4Nb–4Ta alloy after implantation in rat tibia, Biomaterials 22(6) (2001) 599–607.##[29] Y. Okazaki, S. Rao, Y. Ito, T. Tateishi, Corrosion resistance, mechanical properties, corrosion fatigue strength and cytocompatibility of new Ti alloys without Al and V, Biomaterials 19(13) (1998) 1197–1215.##[30] P. Zysset, X. Guo, C. Hoffler, K. Moore, S. Goldstein, Mechanical properties of human trabecular bone lamellae quantified by nanoindentation, Technology and Health Care 6(5-6) (1998) 429–432.##[31] M. Karthega, V. Raman, N. Rajendran, Influence of potential on the electrochemical behaviour of β titanium alloys in Hank’s solution, Acta biomaterialia 3(6) (2007) 1019–1023.##[32] Y. Tanaka, M. Nakai, T. Akahori, M. Niinomi, Y. Tsutsumi, H. Doi, T. Hanawa, Characterization of air-formed surface oxide film on Ti–29Nb–13Ta–4.6 Zr alloy surface using XPS and AES, corrosion Science 50(8) (2008) 2111–2116.##[33] P. Laheurte, F. Prima, A. Eberhardt, T. Gloriant, M. Wary, E. Patoor, Mechanical properties of low modulus β titanium alloys designed from the electronic approach, Journal of the mechanical behavior of biomedical materials 3(8) (2010) 565–573.##[34] A. Azushima, R. Kopp, A. Korhonen, D.-Y. Yang, F. Micari, G. Lahoti, P. Groche, J. Yanagimoto, N. Tsuji, A. Rosochowski, Severe plastic deformation (SPD) processes for metals, CIRP annals 57(2) (2008) 716–735.##[35] I. J. Beyerlein, L. S. Tóth, Texture evolution in equal-channel angular extrusion, Progress in Materials Science 54(4) (2009) 427–510.##[36] Y. Saito, H. Utsunomiya, N. Tsuji, T. Sakai, Novel ultra-high straining process for bulk materials—development of the accumulative roll-bonding (ARB) process, Acta materialia 47(2) (1999) 579–583.##[37] R. Hebert, J. Perepezko, Deformation-induced synthesis and structural transformations of metallic multilayers, Scripta materialia 50(6) (2004) 807–812.##[38] G. Dinda, H. Rösner, G. Wilde, Synthesis of bulk nanostructured Ni, Ti and Zr by repeated cold-rolling, Scripta materialia 52(7) (2005) 577–582.##[39] R. Zhang, V. L. Acoff, Processing sheet materials by accumulative roll bonding and reaction annealing from Ti/Al/Nb elemental foils, Materials Science and Engineering: A 463(1-2) (2007) 67–73.##[40] N. Tsuji, R. Ueji, Y. Minamino, Nanoscale crystallographic analysis of ultrafine grained IF steel fabricated by ARB process, Scripta Materialia 47(2) (2002) 69–76.##[41] N. Kamikawa, T. Sakai, N. Tsuji, Effect of redundant shear strain on microstructure and texture evolution during accumulative roll-bonding in ultralow carbon IF steel, Acta Materialia 55(17) (2007) 5873–5888.##[42] M. Shaarbaf, M. R. Toroghinejad, Nano-grained copper strip produced by accumulative roll bonding process, Materials Science and Engineering: A 473(1-2) (2008) 28–33.##[43] P. Hsieh, J. Huang, Y. Hung, S. Chou, J. Jang, Characterization on nanocrystallization and amorphization evolution in Zr–X alloys during ARB process, Materials chemistry and physics 88(2-3) (2004) 364–376.##[44] D. Raducanu, E. Vasilescu, V. Cojocaru, I. Cinca, P. Drob, C. Vasilescu, S. Drob, Mechanical and corrosion resistance of a new nanostructured Ti–Zr–Ta–Nb alloy, Journal of the mechanical behavior of biomedical materials 4(7) (2011) 1421–1430.##[45] J. Tafel, Über die Polarisation bei kathodischer Wasserstoffentwicklung, Zeitschrift für physikalische Chemie 50(1) (1905) 641–712.##[46] M. Khamehchi, A. Chkhenkeli, Influence of Ionic Size on the concentration of Ag+ and Zn2+ in Simulated Body Fluid: Modeling and Monte Carlo Simulation with Dental Applications, Journal of Composites and Compounds 6(21) (2024).</REF>
          </REFRENCE>
        </REFRENCES>
      </ARTICLE>
    </ARTICLES>
  </ISCJOURNAL>
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